The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl     

Geraldo Magela da Costa  Gabriel de Oliveira Polli  Márcio A. Kahwage  Eddy de Grave  Antônio Claret Soares Sabioni  Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   

Construction Problems on the Karstified Limestone Tuffs of Condeixa, Central Portugal: A Case Study     

M. Quinta Ferreira  J. L. Velho 《Geotechnical and Geological Engineering》2006,24(1):101-116

During the excavations for the foundations of a three storey building on the limestone tuffs of Condeixa, Central Portugal, a large dissolution fissure and smaller dissolution voids were found. Since the area has never been the subject of engineering geology investigation, it was decided to evaluate the risk associated with the construction of the building. These limestone tuffs were formed in a continental environment by the precipitation of calcite carried by the water coming from the large limestone body in the east. The precipitated calcite mixed with the terrigenous materials and around trunks and leaves of plants, originating a very heterogeneous and porous ground, which is characteristic of limestone tuffs. The study started with a detailed geological survey followed by a large number of destructive drillings, located essentially under the pad foundations. The results revealed several karstic cavities with serious problems for the building foundations and the structure, and many smaller dissolution cavities, often filled with clayey soils. The ground treatment solutions used included, dental cleaning, filling with concrete or granular material the dissolution structures accessible at the level of the foundation, reinforcement of the footing and the structure of the building and adding a continuous foundation beam to hold the foundations together. The cost of the engineering geology study, site investigation, ground treatment, and the reinforcement of the foundation and building, increased the total construction cost from 2%, at the design stage, to 4.8%.  相似文献   

桩锚支挡体系在广西寨-任二级公路高边坡治理工程中的应用   总被引：3，自引：0，他引：3  

胡华敏  胡杰刚  俞敏  全洪波  兰高 《中国地质灾害与防治学报》2006,17(3):150-153

(六)寨-(水)任二级公路施工后,滑坡、坍塌、崩塌现象甚多,边坡治理迫在眉睫。桩锚支挡体系是一项主动性加固边坡技术,具结构轻巧、用材合理、施工简单、工期短、费用低等特点。论文通过其在(六)寨-(水)任二级公路K56段高边坡治理工程中的应用,对桩锚支挡体系的设计及施工要点作了介绍。  相似文献   

Effect of heat treatment on tourmaline from Brazil   总被引：4，自引：0，他引：4  

Cristiane Castañeda  Sigrid G. Eeckhout  Geraldo Magela da Costa  Nilson F. Botelho  Eddy De Grave 《Physics and Chemistry of Minerals》2006,33(3):207-216

The crystal-chemical behaviour of tourmaline from Araçuaí, Minas Gerais state, Brazil, when subjected to heating in air atmosphere has been studied by several techniques, including EMPA, UV–Vis, TGA, and Mössbauer spectroscopy. The tourmaline samples are typically intermediate members of the elbaite-schorl series. The origin of colour and of its change after treatment has been discussed in terms of local disorder, presence of metal transition elements, oxidation of ferrous iron at the octahedral site, and simultaneous trap of the excess electron. These findings may be used to enhance the colour in tourmaline crystals or generate wanted colour changes.  相似文献   

旧供水井化学处理方法介绍--以加德满都市旧供水井修复为例   总被引：1，自引：0，他引：1  

章伟民 《水文地质工程地质》2005,32(6):100-101,107

本文以加德满都市旧供水井修复项目为例,针对因滤水管缝隙被化学物质堵塞,导致井出水量逐年减少的旧供水井。通过井下电视摄像系统检查,采用六偏磷酸钠、氨基黄酸等有机酸,结合刷洗、高压喷射等机械方法进行处理,使旧供水井出水量得到明显提高。  相似文献   

非等截面桩超声波成孔质量检测     

韩亮 《物探与化探》2005,29(2):185-188

分析了非等截面超声波成孔质量检测的几个主要影响因素,给出了相应得改进措施。用工程实例说明超声波反射技术是一种保证非等截面桩成孔质量和成桩质量必不可少的检测方法。  相似文献   

利用钻孔超声成像的图像特征进行岩石风化程度分类   总被引：2，自引：0，他引：2  

孔广胜 《物探与化探》2005,29(4):367-368,373

钻孔超声成像方法能精确地反映井壁的光滑情况, 进而判断岩石的风化发育程度, 确定风化层的厚度。阐述了钻孔超声成像的走时和振幅图像特征, 给出了1个在香港地区的应用实例。  相似文献   

超声与振荡提取沉积物中松散结合态磷的比较     

罗俊凌罗爱芹  张月琴 《岩矿测试》2005,24(3):193-196

用超声技术提取沉积物样品中松散结合态磷,并与振荡提取结果进行比较。结果表明,超声提取结果与振荡提取结果大致相当。超声提取耗时短,操作简单易行,测试结果精密度为3.8%(RSD,n=7),可以替代振荡方法提取沉积物中的松散结合态磷。  相似文献   

生物膜处理技术的研究进展   总被引：3，自引：0，他引：3  

吴会中  单欣  赵琛琛 《中国勘察设计》2005,(11):52-54

本文综述了生物膜技术的发展概况及其传质理论,并且对各种类型生物膜反应器的应用和发展作了简要论述,最后提出了生物膜技术的发展方向。  相似文献   

不正常的自记记录处理及在报表编制过程的处理方法     

程爱珍 《气象研究与应用》2002,23(4):61-62

介绍在处理自记观测记录时,对不正常记录及在编制报表时应采取的处理方法。  相似文献